Destruction of herbicide atrazine by solar radiation in photo-Fenton system

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Abstract

The efficiency of solar-induced destruction of herbicide atrazine in natural water and aqueous extract from agrogenic and unbroken soil by using photo-Fenton system was studied in this work. 80-90 % atrazine was removed in all water matrices. Using xenon lamp as a solar simulator, the rate of atrazine destruction was found to be higher in aqueous soil extracts than that observed in natural water. However, no significant difference was found between the destruction dynamics in natural water and soil extracts, exposed to natural solar light. This could be attributed to the higher hydroxyl radical exposure under the higher UV irradiance of the Sun.

About the authors

Christina Mikhailovna Zagibalova

Baikal Institute of Nature Management of SB RAS

Author for correspondence.
Email: kristina-lapohcka@mail.ru

undergraduate student, engineer of the 2nd category, Laboratory of Engineering Ecology, Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences (BINM SB RAS).

6 Sakhyanovoy St.,Ulan-Ude, 670047, Russian Federation

Galina Georgievna Matafonova

Baikal Institute of Nature Management of SB RAS

Email: g.matafonova@gmail.com
SPIN-code: 3674-8648

Doctor of Chemical Sciences, Senior Researcher, Laboratory of Engineering Ecology, Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences (BINM SB RAS).

6 Sakhyanovoy St.,Ulan-Ude, 670047, Russian Federation

Valery Babudorzhievich Batoev

Baikal Institute of Nature Management of SB RAS

Email: vbat@binm.ru
SPIN-code: 5998-3356

Doctor of Biological Sciences, Professor, Chief Researcher, Laboratory of Engineering Ecology, Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences (BINM SB RAS).

6 Sakhyanovoy St.,Ulan-Ude, 670047, Russian Federation

References

  1. Kulikova NA, Lebedeva GF. Gerbicidy i ehkologicheskie aspekty ih primeneniya. M.: Librokom Publ.; 2010.
  2. Normativy kachestva vody vodnyh ob”ektov rybohozyajstvennogo znacheniya, v tom chisle normativov predel’no dopustimyh koncentracij vrednyh veshchestv v vodah vodnyh ob”ektov rybohozyajstvennogo znacheniya. Prikaz Minsel’hoza RF ot 13 dekabrya 2016 goda. http://rulaws.ru/acts/Prikaz- Minselhoza-Rossii-ot-13.12.2016-N-552/
  3. Atrazine and its metabolites in drinking water. Background document for development of WHO Guidelines for Drinking-water Quality. World Health Organization, 2011. http://www.who.int/ water_sanitation_health/dwq/chemicals/antrazine.pdf
  4. Buxton GV, Greenstock CL, Helman WP, Ross WP. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution. J. Phys. Chem. Ref. Data. 1988;17: 513—886.
  5. SkurlatovYI. Opredelyayushchaya rol’ okislitel’no-vosstanovitel’nyh processov v formirovanii kachestva prirodnoj vodnoj sredy. Uspekhihimii. 1991;3: 575—580.
  6. Mostofa KMG, Liu C-Q, Sakugawa H, Vione D, Minakata D, Wu F. Photoinduced and microbial generation of hydrogen peroxide and organic peroxides in natural waters. Photobiogeochemistry of Organic Matter. Principles and Practices in Water Environments. Springer-Verlag Berlin Heidelberg; 2013: 139—207.
  7. GOST 26423—85. Pochvy. Metody opredeleniya udel’noj ehlektricheskoj provodimosti, pH i plotnogo ostatka vodnoj vytyazhki; vved. s 01.01.1986 (popr. ot 03.06.2011). M.: Standartinform Publ.; 2011.
  8. Matafonova G, Batoev V. Comparison of energy requirements for removal of organic micropollutants from lake water and wastewater effluents by direct UV and UV/H2O2 using excilamp. Desal. Wat. Treat. 2017;85: 92—102.
  9. Grčić I, Vujević D, Koprivanac N. Modeling the mineralization and discoloration in colored 2– systems by (US)Fe2+/H2O2/S2O8 2010;157: 35—44. processes: A proposed degradation pathway. Chem. Eng. J.

Copyright (c) 2018 Zagibalova C.M., Matafonova G.G., Batoev V.B.

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