Environmental and geochemical assessment of sealed soils in the Eastern Moscow
- Authors: Nikiforova E.M.1, Kosheleva NE1, Khaybrakhmanov T.S.2
- Lomonosov Moscow State University
- Engineering and Technology Center “SCANEX”
- Issue: Vol 25, No 4 (2017)
- Pages: 480-509
- Section: Articles
- URL: https://journals.rudn.ru/ecology/article/view/18616
- DOI: https://doi.org/10.22363/2313-2310-2017-25-4-480-509
Sealed with road coverings soils in the Eastern Administrative District (EAD) of Moscow were studied, their morphological and physico-chemical properties have been established in various landuse zones, their ecological and geochemical state and level of readily soluble salts and priority organic pollutants - petroleum products (PP) and benzo(a)pyrene (BaP) as compared with background and open urban soils. The article is based on the results of soil-geochemical survey of ekranozems in September 2016 and previously obtained analytical data from an unsealed territory in the southern part of the EAD. A mapping technique was developed and a map of degree of soil sealing in the EAD was compiled. The morphological features and the basic properties of ekranozem’s horizons in different land-use zones of the EAD were determined. They have a low content of organic matter (2,24%), an alkaline pH (8,0), light loamy texture. Despite the use of de-icing salts and mineral fertilizers, the upper part of the profile of the sealed soils is not saline, salts accumulate mainly in the middle and lower parts of the profile, forming maxima in the RAT horizon. Screening of soils with asphalt concrete is not an obstacle to the penetration of technogenic flows of polluting substances - salts, PP, BaP, capable of accumulating in increased concentrations and forming pronounced technogenic anomalies. The average BaP content in the sealed soils exceeds the background level by 56 times, and the MPC - by 9,6 times. The permissible content of PP in ekranozems is exceeded by 9,5 times. However, in comparison with unsealed soils, the content of BaP and PP in ekranozems is 3,5 times less. The vertical distribution of the BaP is, as a rule, uniform, with the exception in the industrial zone, and for the PP it is accumulative with several well-defined maxima in different parts of the profile. As a result of lateral migration, BaP and PP accumulate in the sealed soils of the lower parts of the slopes, where they form accumulations on organomineral and sorption-sedimentative geochemical barriers. High-level man-made accumulations of hydrocarbons are formed mainly in the sealed soils of industrial and transport zones. When opening the asphalt, risks associated with the migration of hydrocarbons to other components of the landscape, including them in the biological cycle and food chains may appear.
About the authors
Elena Mihajlovna NikiforovaLomonosov Moscow State University
Author for correspondence.
candidate of geographical Sciences, senior researcher of the Department of landscape Geochemistry and soil geography, Geographical faculty of Moscow state UniversityLeninskie Gory, 1, Moscow, Russia, 119991
N E KoshelevaLomonosov Moscow State University
doctor of geographical Sciences, leading researcher of the Department of landscape Geochemistry and soil geography, Geographical faculty of Moscow state UniversityLeninskie Gory, 1, Moscow, Russia, 119991
Timur Salavatovich KhaybrakhmanovEngineering and Technology Center “SCANEX”
vice-leader of a department in the group of companies “SCANEX”Kiev highway p. 1. Business Park «Rumyantsevo», A, 8 entrance, office 732, Moscow, Russia, 108811
- Glazovskaya M.A., Solntseva N.P., Gennadiev A.N. Techno-pedogenesis: forms of manifestations. Success of soil science. Moscow: Nauka, 1986. P. 106—112. (In Russ).
- Gerasimova M.I., Stroganova M.N., Mozharova N.V., Prokofieva Т.V. Anthropogenic soils (genesis, geography, reclamation). Moscow: Oikumena, 2003. 266 p. (In Russ).
- FAO/ISRIC. Guidelines for Soil Profile Description. 3th ed. Food and Agriculture Organization of the Union Nations. Rome, 2000.
- Gesentsvey L.B., Gorelyshev N.V., Boguslavsky A.M., Korolev I.V. Road asphalt concrete. Moscow: Transport, 1985. 350 p. (In Russ).
- Manuylov M.B., Moskovkin V.M. Influence of surface run-off (rain and thawed waters) on the ecological and technogenic situation in cities. Water and ecology: problems and solutions. 2016. 2: 35—47 (In Russ).
- Wessolek G. Sealing of soils. Urban ecology, an international perspective on the interaction between humans and nature. Springer, 2008. Pp. 161—179.
- Burghardt W. Soil sealing ways, constraints, benefits and management. Soils within Cities. Global approaches to their sustainable management — composition, properties, and functions of soils of the urban environment. M.J. Levin, K.-H.J. Kim, J.L. Morel, W. Burghardt, P. Charzynski, R.K. Shaw, editors. IUSS Working Group SUITMA. 2017. IV. P. 169—175.
- Soils within Cities. Global approaches to their sustainable management — composition, properties, and functions of soils of the urban environment. M.J. Levin, K.-H.J. Kim, J.L. Morel, W. Burghardt, P. Charzynski, R.K. Shaw, editors. IUSS Working Group SUITMA. 2017. IV. 275 p.
- Stroganova M.N., Prokofyeva Т.V. Influence of road covering on urban soils. Moscow University Soil Science Bulletin. 1995. 2: 3—11.
- Prokofyeva Т.V. Urban soil, sealed with road surfaces (based on the example of Moscow). PhD Thesis. Moscow: MSU, faculty of soil science, 1998. 24 p. (In Russ).
- Zabelina O.N., Zlyvko A.S. Biological activity of the sealed soil on urbanized territories. Progresses of modern natural science. 2015. No. 5. Pp. 167—170. (In Russ).
- Prokofyeva T.V., Martynenko I.A., Ivannikov F.A. Classification of Moscow soils and parent materials and its possible inclusion in the classification system of Russian soils. Eurasian Soil Science. 2011. 44 (5): 561—571.
- European Environment Agency. URL: http://www.eea.europa.eu/articles/ urban-soil-sealingin-europe (date of access: 14.12.2017).
- Kasimov N.S., Vlasov D.V., Kosheleva N.E., Nikiforova E.M. Geochemistry of the landscapes in the Eastern Moscow. Moscow: APR, 2016. 276 p. (In Russ).
- Bityukova V.R., Saulskaya T.D. Change in the anthropogenic impact of industrial zones in Moscow in the post-Soviet period. Vestnik Moskovskogo Universiteta, Seriya 5, Geografiya. 2017. 3. (In Russ).
- Kosheleva N.E., Nikiforova E.M. Long-Term Dynamics of Urban Soil Pollution with Heavy Metals in Moscow. Applied and Environmental Soil Science. 2016. 2016: 10 pp. doi: 10.1155/2016/5602795
- Regions and cities of Russia: an integral assessment of the environmental state. N.S. Kasimov, V.R. Bityukova, S.M. Malkhazova et al. Moscow: IP Filimonov MV, 2014. 560 p. (In Russ).  Nikiforova E.M., Kasimov N.S., Kosheleva N.E. Long-term dynamics of the anthropogenic salinization of soils in Moscow (by the example of the Eastern district). Eurasian Soil Science. 2014. 47 (3): 203—215.
- Sister V.G., Koretsky V.E. Engineering and environmental protection of the water system of the northern megapolis in winter. Moscow: TsentrMGUIE, 2004. 159 p. (In Russ).
- Khomyakov D.M. Moscow does not believe in tears. On the de-icing reagents used in Moscow for the winter period and their volume. The Road Power, 2015. 58: 91—95 (In Russ).
- Smagin A.V., Azovtseva N.A., Smagina M.V., Stepanov A.L., Myagkova A.D., Kurbatova A.S. Criteria and methods to assess the ecological status of soils in relation to the landscaping of urban territories. Eurasian Soil Science. 2006. 39 (5): 539—551. GEOECOLOGY
- Pikovsky Yu.I., Ismayilov N.M., Dorokhova M.F. Fundamentals of oil and gas geoecology. Moscow: INFRA-M, 2015. 400 p. (In Russ).
- Geochemistry of polycyclic aromatic hydrocarbons in rocks and soils. A.N. Gennadiyev, Yu.I. Pikovsky, editors. Moscow: Moscow University Publishing House, 1996. 192 p. (In Russ).
- Jacob J. The significance of polycyclic aromatic hydrocarbons as environmental carcinogens. 35 years research on PAH — a retrospective. Polycycl. Aromat. Compd. 2008; 28 (4-5): 242—272. http://dx.doi.org/10.1080/ 10406630802373772
- Khalili N.R., Scheff P.A., Holsen T.M. PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions. Atmos. Environ. 1995; 29: 533—542.
- Larsen R.K., Baker J.E. Source apportionment of polycyclic aromatic hydrocarbons in the urban atmosphere: a comparison of three methods. Environ. Sci. Technol. 2003. 37 (9): 1873—1881. URL: http://dx.doi.org/10.1021/es0206184 (date of access: 14.12.2017).
- Wild S.R., Jones K.C. Polynuclear aromatic hydrocarbons in the United Kingdom environment: a preliminary source inventory and budget. Environ. Pollut. 1995. 88 (1): 91—108. URL: http:// dx.doi.org/10.1016/0269-7491(95) 91052-M (date of access: 14.12.2017).
- Wania F., MacKay D. Tracking the Distribution of Persistent Organic Pollutants. Environ. Sci. Technol. 1996. 30 (9): 390A—396A. URL: http://dx.doi.org/10.1021/ es962399q (date of access: 14.12.2017).
- Trapido M. Polycyclic aromatic hydrocarbons in Estonian soil: contamination and profiles. Environ. Pollut. 1999. 105 (1): 67—74. URL: http://dx.doi.org/10.1016/ S0269-7491(98)00207-
- (date of access: 14.12.2017).
- Fernández P., Vilanova R.M., Martínez C., Appleby P., Grimalt J.O. The Historical Record of Atmospheric Pyrolytic Pollution over Europe Registered in the Sedimentary PAH from Remote Mountain Lakes. Environ. Sci. Technol. 2000. 34 (10): 1906—1913. URL: http://dx.doi. org/10.1021/es9912271 (date of access: 14.12.2017).
- Nam J.J., Sweetman A.J., Jones K.C. Polynuclear aromatic hydrocarbons (PAHs) in global background soils. J. Environ. Monit. 2009. 11 (1): 45—48. URL: http://dx.doi.org/10.1039/ B813841A (date of access: 14.12.2017).
- Nikiforova E.M., Kosheleva N.E. Polycyclic aromatic hydrocarbons in urban soils (Moscow, Eastern District). Eurasian Soil Science. 2011. 44 (8): 1018—1030.
- Ecological atlas of Moscow. Moscow: ABF/ABF Publishing House, 2000. 96 p. (In Russ).
- Kasimov N.S., Nikiforova E.M., Kosheleva N.E., Khaybrakhmanov Т.S. Geoinformation landscape-geochemical mapping of urban areas (on the example of EAD in Moscow). 1. Cartographic support. Geoinformatics. 2012. 4: 37—45 (In Russ).
- Orlov D.S. Chemistry of soils. Moscow: Moscow University Publishing House, 1985. 376 p. (In Russ).
- Targulyan V.O., Kozlovsky F.I., Karavaeva N.A., Aleksandrovsky A.L. The problem of soil evolution in Dokuchaev soil science. 100 years of genetic soil science. Moscow: Nauka, 1986. P. 104—117. (In Russ).
- Solntseva N.P. Morphogenetic analysis of technogenically transformed soils. Eurasian Soil Science. 1990. 1: 96—101 (In Russ).
- Ecological Requirements for Soils and Grounds in Moscow. N.F. Ganjara, editor. Moscow: Agroconsult, 2005. 32 pp. (In Russ).
- Pikovsky Yu.I., Gennadiev A.N., Krasnopeeva A.A., Puzanova Т.А. Natural and technogenic hydrocarbon geochemical fields in soils: concept, typology, indicator significance. Geochemistry of landscapes and geography of soils. 100th Anniversary of the Birth of M.A. Glazovskaya. N.S. Kasimov, M.I. Gerasimova, editors. Moscow: APR, 2012. P. 236—258. (In Russ).
- Zabelina О.N. Integral toxicity of urban sealed soils. Topical issues of modern science. 2015. 8: 15—18. (In Russ).
- Stroganova M.N., Myagkova A.D., Prokofyeva Т.V. The Role of Soils in Urban Ecosystems. Eurasian Soil Science. 1997. 8: 124—129.
- Stroganova M.N. Urban Soils: Genesis, Systematics and Ecological Importance (by the Example of Moscow). Diss. Thesis of Doctor of Biological sciences. Moscow: MSU, 1998. 71 p. (In Russ).
- Glazovskaya M.A. Geochemical barriers in soils: typology, functional features and ecological significance. Geochemistry of landscapes and geography of soils. 100th Anniversary of the Birth of M.A. Glazovskaya. N.S. Kasimov, M.I. Gerasimova, editors. Moscow: APR, 2012. Pp. 26—44. (In Russ).
- Kasimov N.S., Kosheleva N.E., Nikiforova E.M., Vlasov D.V. Benzo[a]pyrene in urban environments of eastern Moscow: pollution levels and critical loads. Atmospheric Chemistry and Physics. 2017. 17: 2217—2227. doi: 10.5194/acp-17-2217-2017
- On the state of the environment in Moscow in 2014. A.O. Kulbachevsky, editor. Мoscow: DP and ООS; NIA Nature, 2015. 384 p. (In Russ).
- Kosheleva N.E., Nikiforova E.M. Long-term dynamics and factors of accumulation of benzo(a) pyrene in urban soils (by the example of the EAD in Moscow). Moscow University Soil Science Bulletin. 2011. 66 (2): 65—74 (In Russ).
- Chernyanskii S.S., Alekseeva T.A., Gennadiev A.N., Pikovskii Y.I. Organic profile of soddy-gley soil strongly polluted by polycyclic aromatic hydrocarbons. Eurasian Soil Science. 2001. 34 (11): 1170—1179.
- Burghardt W., von Bertrab M. Dialeimmasol, urban soil of pavements. J Soils & Sediments. 2016. (11): 2500—2513. doi: 10.1007/s11368-016-1526-y
- Vasenev V.I., Stoorvogel J.J., Ibatulina S.A., Romzaykina O.N., Moedt E., Kanaeva S.A., Ivashchenko K.V., Ananyeva N.D., Dovletyarova E.A. Urbanization in New Moscow: challenges and perspectives for soil resources. SUITMA 9. 9th international congress “Soils of Urban, Industrial, Traffic, Mining and Military Areas”. Russia, Moscow, 22—26 May 2017. Abstract book. P. 224—228.