Resonant Atom Model and the Formation of Valence Bonds
- Authors: Magarshak Y.B.1
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Affiliations:
- MathTech Inc
- Issue: No 1-2 (2007)
- Pages: 100-116
- Section: Physics and Astronomy
- URL: https://journals.rudn.ru/miph/article/view/51129
- EDN: https://elibrary.ru/JWJLRL
- ID: 51129
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Abstract
The nature of the valence bond is traditionally attributed to the displacement of electronic orbitals in space between interacting atoms. At the same time, a number of experimental facts, in particular, the existence of four-dimensional structural symmetry between the filling of electron shells and periodical properties of elements require a change in the standard valence concept. A model in which valence bonds are caused by the resonant interaction between the shell electrons of one atom and the protons of another atom seems to be more adequate.
References
- Pauling L. The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry. - Ithaca: Cornell Univ. Press, 1939.
- Levine I. N. Quantum Chemistry. - 5th ed. edition. - Englewood Cliffs: Prentice Hall, 2000.
- Pauling L. The Nature of the Chemical Bond // J. Am. Chem. Soc. - Vol. 53. - 1931. - Pp. 1367-1400.
- Mendeleev D. On the Relationship of the Properties of the Elements to Their Atomic Weights // Zh. Russ. Fiz.-Khim. O-va. - Vol. 1. - 1869. - Pp. 60-77.
- Mendeleev D. On the Relationship of the Properties of the Elements to Their Atomic Weights // Z. Chem. - Vol. 12. - 1869. - Pp. 405-406.
- Magarshak Y., Malinsky J. A Three-Dimensional Periodic Table // Nature. - Vol. 360. - 1992. - Pp. 114-115.
- Magarshak Y. Four-Dimensional Pyramidal Structure of the Periodic Properties of Atoms and Chemical Elements // Sci. Isr. Technol. Adv. - Vol. 7, No 1, 2. - 2006. - Pp. 134-150.
- Bogomolov F., Magarshak Y. On Commuting Operators Related to Asymptotic Symmetries in the Atomic Theory // Sci. Isr. Technol. Adv. - Vol. 7, No 3. - 2006.
- Pauling L. The Shared-Electron Chemical Bond // Proc. Natl. Acad. Sci. USA. - Vol. 14. - 1928. - Pp. 359-362.
- Mandelshtam L. I., Tamm I. E. The Uncertainty Relation between Energy and Time in Nonrelativistic Quantum Mechanics // Izv. Akad. Nauk SSSR, Ser. Fiz. - Vol. 9. - 1945. - Pp. 122-128.
- Landau L. D., Lifshitz E. M. Nonrelativistic Quantum Mechanics. - Moscow: Nauka, 1974.
- Heitler W., London F. Wechselwirkung neutraler Atome und homopolare Bindung nach der Quantenmechanik (Interaction Between Neutral Atoms and Homopolar Binging According to Quantum Mechanics) // Z. Phys. - Vol. 44. - 1927. - Pp. 455-472.
- London F. Probleme der Modernen Physik / Ed. by S. Herzel. - Leipzig: Sommerfeld Festschrift, 1928. - Pp. 104-113.
- Polanyi M., Wigner E. // Z. Phys. Chem. A. - Vol. 139. - 1928. - P. 439.
- Eyring H., Polanyi M. On Simple Gas Reactions // Z. Phys. Chem. B. - Vol. 12. - 1931. - P. 279.
- van’t Hoff J. H. Etudes de Dynamiques Chimiques. - Amsterdam: F. Muller and Co., 1884. - P. 114.
- Arrhenius S. On Simple Gas Reactions // Z. Phys. Chem. - Vol. 4. - 1889. - P. 226.
- Slater J. C. Directed Valence in Polyatomic Molecules // Phys. Rev. - Vol. 37. - 1931. - P. 481.
- Hund F. Linienspektren und Periodisches System der Elemente. - Berlin: Springer, 1927.
- Hund F. // Z. Phys. - Vol. 52. - 1929. - P. 606.
- Mulliken R. S. // Rev. Mod. Phys. - Vol. 2. - 1930. - Pp. 99-100.
- Mulliken R. S. // Phys. Rev. - Vol. 33. - 1929. - P. 507.
- Mulliken R. S. // Phys. Rev. - Vol. 30. - 1927. - P. 138.
- Mulliken R. S. // Phys. Rev. - Vol. 33. - 1929. - P. 738.
- Mulliken R. S. // Phys. Rev. - Vol. 36. - 1930. - P. 1449.
- Hund F. // Z. Phys. - Vol. 63. - 1930. - Pp. 719-751.
- The Chemical Bond: Structure and Dynamics / Ed. by A. H. Zewail. - Boston: Academic, 1992.
- Zewail A. H. Femtochemistry: Atomic-Scale Dynamics of the Chemical Bond // J. Phys. Chem. A. - Vol. 104. - 2000. - Pp. 5660-5694.
- Femtochemistry and Femtobiology: Ultrafast Events in Molecular Science / Ed. by M. M. Martin, J. T. Hynes. - New York: Elsevier, 2002.
- Sinai Y. G. Dynamical Systems with Elastic Reflections. Ergodic Properties of Dispersing Billiards // Russ. Math. Surveys. - Vol. 25, No 2. - 1970. - Pp. 137- 189.
- Bunimovich L. A., Sinai Y. G. On a Fundamental Theorem in the Theory of Dispersing Billiards // Math. USSR, Sb.19. - Vol. 3. - 1973. - Pp. 407-423.
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